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1

Mechanism of the Thermal Z⇌E Isomerization of a Stable Silene. Experiment and Theory

Zborovsky, Lieby, Kostenko, Arseni, Bravo-Zhivotovskii, Dmitry, Apeloig, Yitzhak

Journal:

Angewandte Chemie

Year:

2019

Language:

english

File:

PDF, 1.13 MB

english, 2019

2

The Syntheses and Molecular Structure of a Branched Oligosilyl Anion with a Record of Nine Silicon Atoms and of the First Branched Oligosilyl Dianion

Yitzhak Apeloig, Gady Korogodsky, Dmitry Bravo-Zhivotovskii, Dieter Bläser, Roland Boese

Journal:

European Journal of Inorganic Chemistry

Year:

2000

Language:

english

File:

PDF, 287 KB

english, 2000

3

Synthese und Molekülstruktur der ersten zweifach koordinierten zweikernigen Quecksilber(I)-Verbindung des Typs RHgHgR

Dmitry Bravo-Zhivotovskii, Michael Yuzefovich, Michael Bendikov, Karl Klinkhammer, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

1999

Language:

german

File:

PDF, 90 KB

german, 1999

4

The Synthesis and Molecular Structure of the First Two-Coordinate, Dinuclear σ-Bonded Mercury(I) RHgHgR Compound

Dmitry Bravo-Zhivotovskii, Michael Yuzefovich, Michael Bendikov, Karl Klinkhammer, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

1999

Language:

english

File:

PDF, 100 KB

english, 1999

5

Verzweigte, sternförmige Polysilyllithiumverbindungen: der Einfluss von β-Silylsubstitution und Komplexierung auf die Molekülstruktur

Yitzhak Apeloig, Michael Yuzefovich, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Dieter Bläser, Roland Boese

Journal:

Angewandte Chemie

Year:

2001

Language:

german

File:

PDF, 100 KB

german, 2001

6

The Synthesis of the First Compound with Li-Si-Hg Bonding: [{Li(iPr3Si)2Si}2Hg]—a Source for the [Li(iPr3Si)2Si]. Radical

Dmitry Bravo-Zhivotovskii, Michael Yuzefovich, Nadejda Sigal, Gady Korogodsky, Karl Klinkhammer, Boris Tumanskii, Alex Shames, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2002

Language:

english

File:

PDF, 143 KB

english, 2002

7

Branched Star-Type Polysilyllithium Compounds: The Effects of β-Silyl Substitution and of Complexation on Their Molecular Structure

Yitzhak Apeloig, Michael Yuzefovich, Michael Bendikov, Dmitry Bravo-Zhivotovskii, Dieter Bläser, Roland Boese

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 118 KB

english, 2001

8

The Synthesis of the First Compound with Li-Si-Hg Bonding: [{Li(iPr3Si)2Si}2Hg]—a Source for the [Li(iPr3Si)2Si]. Radical

Dmitry Bravo-Zhivotovskii, Michael Yuzefovich, Nadejda Sigal, Gady Korogodsky, Karl Klinkhammer, Boris Tumanskii, Alex Shames, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2002

Language:

english

File:

PDF, 95 KB

english, 2002

9

The Direct Synthesis of a Silene–Organometallic Complex

Dmitry Bravo-Zhivotovskii, Hanan Peleg-Vasserman, Monica Kosa, Gregory Molev, Mark Botoshanskii, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2004

Language:

english

File:

PDF, 181 KB

english, 2004

10

Nonsolvated, Aggregated 1,1-Dilithiosilane and the Derived Silyl Radicals

Dmitry Bravo-Zhivotovskii, Ilya Ruderfer, Semyon Melamed, Mark Botoshansky, Boris Tumanskii, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2005

Language:

english

File:

PDF, 141 KB

english, 2005

11

[{(tBu2Me)2Si}3Li4]2−: An Aggregated Dianion of a 1,1-Dilithiosilane with a Unique Structural Motif

Dmitry Bravo-Zhivotovskii, Ilya Ruderfer, Semyon Melamed, Mark Botoshansky, Asher Schmidt, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2006

Language:

english

File:

PDF, 100 KB

english, 2006

12

The Synthesis and Isolation of a Metal-Substituted Bis-silene

Dmitry Bravo-Zhivotovskii, Roman Dobrovetsky, Dmitry Nemirovsky, Victoria Molev, Michael Bendikov, Gregory Molev, Mark Botoshansky, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2008

Language:

english

File:

PDF, 358 KB

english, 2008

13

Radical Polymerization of the Silene (Me3Si)2SiCR2 by Hydrogen Transfer from a Trimethylsilyl Group

Dmitry Bravo-Zhivotovskii, Semyon Melamed, Victoria Molev, Nadejda Sigal, Boris Tumanskii, Mark Botoshansky, Gregory Molev, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2009

Language:

english

File:

PDF, 305 KB

english, 2009

14

Isolation of Silenolates (R3Si)2SiC(OLi)Ad with a Doubly Bonded Silicon Atom

Roman Dobrovetsky, Lieby Zborovsky, Dennis Sheberla, Mark Botoshansky, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2010

Language:

english

File:

PDF, 419 KB

english, 2010

15

Synthesis, Isolation, and Characterization of 1,1-DiGrignard and 1,1-Dizincio Silanes

Roman Dobrovetsky, Dr. Dmitry Bravo-Zhivotovskii, Dr. Boris Tumanskii, Dr. Mark Botoshansky, Prof. Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2010

Language:

english

File:

PDF, 370 KB

english, 2010

16

The Direct Synthesis of a Silene–Organometallic Complex

Dmitry Bravo-Zhivotovskii, Hanan Peleg-Vasserman, Monica Kosa, Gregory Molev, Mark Botoshanskii, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2004

Language:

english

File:

PDF, 181 KB

english, 2004

17

Nonsolvated, Aggregated 1,1-Dilithiosilane and the Derived Silyl Radicals

Dmitry Bravo-Zhivotovskii, Ilya Ruderfer, Semyon Melamed, Mark Botoshansky, Boris Tumanskii, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2005

Language:

english

File:

PDF, 142 KB

english, 2005

18

[{(tBu2Me)2Si}3Li4]2−: An Aggregated Dianion of a 1,1-Dilithiosilane with a Unique Structural Motif

Dmitry Bravo-Zhivotovskii, Ilya Ruderfer, Semyon Melamed, Mark Botoshansky, Asher Schmidt, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2006

Language:

english

File:

PDF, 101 KB

english, 2006

19

The Synthesis and Isolation of a Metal-Substituted Bis-silene

Dmitry Bravo-Zhivotovskii, Roman Dobrovetsky, Dmitry Nemirovsky, Victoria Molev, Michael Bendikov, Gregory Molev, Mark Botoshansky, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2008

Language:

english

File:

PDF, 358 KB

english, 2008

20

Radical Polymerization of the Silene (Me3Si)2SiCR2 by Hydrogen Transfer from a Trimethylsilyl Group

Dmitry Bravo-Zhivotovskii, Semyon Melamed, Victoria Molev, Nadejda Sigal, Boris Tumanskii, Mark Botoshansky, Gregory Molev, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2009

Language:

english

File:

PDF, 306 KB

english, 2009

21

Isolation of Silenolates (R3Si)2SiC(OLi)Ad with a Doubly Bonded Silicon Atom

Roman Dobrovetsky, Lieby Zborovsky, Dennis Sheberla, Mark Botoshansky, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2010

Language:

english

File:

PDF, 438 KB

english, 2010

22

Synthesis, Isolation, and Characterization of 1,1-DiGrignard and 1,1-Dizincio Silanes

Roman Dobrovetsky, Dr. Dmitry Bravo-Zhivotovskii, Dr. Boris Tumanskii, Dr. Mark Botoshansky, Prof. Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2010

Language:

english

File:

PDF, 373 KB

english, 2010

23

ChemInform Abstract: Transformation of Organosilicon-Loaded Alumina Gel to Homogeneous Aluminosilicates: A Solid-State NMR Study.

Dmitry Bravo-Zhivotovskii, Semyon Melamed, Yitzhak Apeloig, Asher Schmidt, Sharona Melchior, Gennady E. Shter, Gideon S. Grader

Journal:

Year:

2001

File:

PDF, 31 KB

2001

24

The effect of substituents on the structure and reactivity of organogermanium anions

S.D. Pigarev, D.A. Bravo-Zhivotovskii, I.D. Kalikhman, N.S. Vyazankin, M.G. Voronkov

Journal:

Journal of Organometallic Chemistry

Year:

1989

Language:

english

File:

PDF, 722 KB

english, 1989

25

Sila- and germa-enolate anions. The reaction of acylgermanes with triethylgermyllithium

I.S. Biltueva, D.A Bravo-Zhivotovskii, I.D. Kalikhman, V.Yu. Vitkovskii, S.G. Shevchenko, N.S. Vyazankin, M.G. Voronkov

Journal:

Journal of Organometallic Chemistry

Year:

1989

Language:

english

File:

PDF, 125 KB

english, 1989

26

Synthesis and the electronic spectra of the first ß-ketoacylsilanes and their lithium enolates: new insights into hyperconjugation in acylsilanes and their enolates

Yitzhak Apeloig, Ilya Zharov, Dmitry Bravo-Zhivotovskii, Yuri Ovchinnikov, Yuri Struchkov

Journal:

Journal of Organometallic Chemistry

Year:

1995

Language:

english

File:

PDF, 853 KB

english, 1995

27

Spectroscopic studies of the role of silyl radicals in photolysis of polysilanes

D. Azinović, D. Bravo-Zhivotovskii, M. Bendikov, Y. Apeloig, B. Tumanskii, S. Vepřek

Journal:

Chemical Physics Letters

Year:

2003

Language:

english

File:

PDF, 382 KB

english, 2003

28

Reactions of triethylgermyllithium with N,N-dialkylated carboxamides

D.A. Bravo-Zhivotovskii, S..D Pigarev, I.D. Kalikhman, O.A. Vyazankina, N.S. Vyazankin

Journal:

Journal of Organometallic Chemistry

Year:

1983

Language:

english

File:

PDF, 733 KB

english, 1983

29

Synthesis of the first long-lived bis-silene

Dmitry Bravo-Zhivotovskii, Gady Korogodsky, Yitzhak Apeloig

Journal:

Journal of Organometallic Chemistry

Year:

2003

Language:

english

File:

PDF, 507 KB

english, 2003

30

The effect of aluminium alkoxides on single electron transfer reactions. A convenient synthetic route to (N,N-dialkylcarbomoyl)germanes

A.V. Seleznev, D.A. Bravo-Zhivotovskii, T.I. Vakul'skaya, M.G. Voronkov

Journal:

Year:

1990

Language:

english

File:

PDF, 463 KB

english, 1990

31

Polysilyl radicals: EPR study of the formation and decomposition of star polysilanes

Y. Apeloig, D. Bravo-Zhivotovskii, M. Yuzefovich, M. Bendikov, A. I. Shames

Journal:

Applied Magnetic Resonance

Year:

2000

Language:

english

File:

PDF, 640 KB

english, 2000

32

A novel route to the trisilacyclobutane moiety. A possible silene-disilene reaction

Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig, Yuri Ovchinnikov, Vladimir Igonin, Yuri T. Struchkov

Journal:

Journal of Organometallic Chemistry

Year:

1993

Language:

english

File:

PDF, 682 KB

english, 1993

33

Microstructure Evolution of Nonhydrolytic Alumina Gels

G.S. Grader, Y. de Hazan, Y. Cohen, D. Bravo-Zhivotovskii

Journal:

Journal of Sol-Gel Science and Technology

Year:

1997

Language:

english

File:

PDF, 117 KB

english, 1997

34

Effect of Aging on Nonhydrolytic Alumina Xerogels

G.S. Grader, Y. de Hazan, D. Bravo-Zhivotovskii, G.E. Shter

Journal:

Journal of Sol-Gel Science and Technology

Year:

1997

Language:

english

File:

PDF, 135 KB

english, 1997

35

Radical Activation of SiH Bonds by Organozinc and Silylzinc Reagents: Synthesis of Geminal Dizinciosilanes and Zinciolithiosilanes

Dr. Roman Dobrovetsky, Yosi Kratish, Dr. Boris Tumanskii, Dr. Mark Botoshansky, Dr. Dmitry Bravo-Zhivotovskii, Prof. Yitzhak Apeloig

Journal:

Angewandte Chemie

Year:

2012

Language:

english

File:

PDF, 514 KB

english, 2012

36

Radical Activation of SiH Bonds by Organozinc and Silylzinc Reagents: Synthesis of Geminal Dizinciosilanes and Zinciolithiosilanes

Dr. Roman Dobrovetsky, Yosi Kratish, Dr. Boris Tumanskii, Dr. Mark Botoshansky, Dr. Dmitry Bravo-Zhivotovskii, Prof. Yitzhak Apeloig

Journal:

Angewandte Chemie International Edition

Year:

2012

Language:

english

File:

PDF, 525 KB

english, 2012

37

ChemInform Abstract: A Novel Synthesis of a Germene and of a 1,2-Digermacyclobutane via a Peterson-Type Reaction.

D. BRAVO-ZHIVOTOVSKII, I. ZHAROV, M. KAPON, Y. APELOIG

Journal:

Year:

1996

File:

PDF, 27 KB

1996

38

Synthesis of the monomeric complex (C2H5)3GeLi·(CH3)2NCH2CH2N(CH3)2

O. A. Kruglaya, D. A. Bravo-Zhivotovskii, I. M. Korotaeva, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1975

Language:

english

File:

PDF, 55 KB

english, 1975

39

Transmetalation of triethylsilyl and triethylgermyl compounds with alkali metals

D. A. Bravo-Zhivotovskii, I. D. Kalikhman, O. A. Kruglaya, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1978

Language:

english

File:

PDF, 60 KB

english, 1978

40

The influence of the nature of the solvent on the properties of triethylgermyllithium and its analogs

D. A. Bravo-Zhivotovskii, I. D. Kalikhman, O. A. Kruglaya, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1977

Language:

english

File:

PDF, 63 KB

english, 1977

41

Reaction of triethylgermyllithium with carboxylic acid N,N-dialkylamides

D. A. Bravo-Zhivotovskii, S. D. Pigarev, O. A. Vyazankina, I. D. Kalikhman, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1982

Language:

english

File:

PDF, 267 KB

english, 1982

42

Effect of donor solvents on the properties of triethylgermyllithium and related compounds

D. A. Bravo-Zhivotovskii, I. D. Kalikhman, O. A. Kruglaya, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1979

Language:

english

File:

PDF, 484 KB

english, 1979

43

Spectroscopic study of germanium-containing compounds

N. N. Chipanina, G. N. Sarapulova, D. A. Bravo-Zhivotovskii, S. D. Pigarev, O. A. Byazankina, Yu. I. Frolov, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1984

Language:

english

File:

PDF, 353 KB

english, 1984

44

Complexation of triethylsilyllithium and its analogs with donor ligands

D. A. Bravo-Zhivotovskii, O. A. Kruglaya, I. D. Kalikhman, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1979

Language:

english

File:

PDF, 69 KB

english, 1979

45

Investigation of the ionic forms of triethylgermyllithium in solutions by PMR spectroscopy

I. D. Kalikhman, D. A. Bravo-Zhivotovskii, B. Z. Pertsikov, V. A. Pestunovich, O. A. Kruglaya, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1980

Language:

english

File:

PDF, 389 KB

english, 1980

46

Mass spectra of several acylgermanes

V. Yu. Vitkovskii, D. A. Bravo-Zhivotovskii, S. D. Pigarev, O. A. Vyazankina, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1984

Language:

english

File:

PDF, 188 KB

english, 1984

47

Synthesis of pentaethyldigermyllithium

D. A. Bravo-Zhivotovskii, D. S. Pigaev, O. A. Vyazankina, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1984

Language:

english

File:

PDF, 67 KB

english, 1984

48

First example of a lithium ketyl stable in hydrocarbons

D. A. Bravo-Zhivotovskii, T. I. Vakul'skaya, I. S. Biltueva, N. S. Vyazankin, M. G. Voronkov

Journal:

Russian Chemical Bulletin

Year:

1989

Language:

english

File:

PDF, 81 KB

english, 1989

49

Reaction of benzoyltriethylgermane with triethylgermyllithium

D. A. Bravo-Zhivotovskii, I. S. Biltueva, T. I. Vakul'skaya, N. S. Vyazankin, M. G. Voronkin

Journal:

Russian Chemical Bulletin

Year:

1987

Language:

english

File:

PDF, 90 KB

english, 1987

50

Reactions of dialkylamides of trimethylsilylpropiolic acid with triethylgermyllithium

D. A. Bravo-Zhivotovskii, S. D. Pigarev, O. A. Vyazankina, A. S. Medvedeva, L. P. Safronova, N. S. Vyazankin

Journal:

Russian Chemical Bulletin

Year:

1984

Language:

english

File:

PDF, 187 KB

english, 1984